A Singular Value Decomposition Framework for Retrievals with Vertical Distribution Information from Greenhouse Gas Column Absorption Spectroscopy Measurements

[摘要] We describe a variation of the Optimal Estimation (OE) method for greenhouse gas remote sensing retrievals using a singular value decomposition (SVD) and an uninformative prior. The SVD method is capable of discerning vertical information in column integrated absorption measurements. While traditional Bayesian optimal estimation (OE) assumes a prior distribution in order to regularize the inversion problem, the SVD approach identifies principal components that can be retrieved from the measurement without explicitly specifying a prior mean and prior covariance matrix. We discuss the method, illustrate its use on an integrated path differential absorption CO2 lidar measurement model, and compare it to traditional optimal estimation using numerical simulations. In the absence of forward model error, the mathematics behind the SVD method guarantee it to be bias-free, which is confirmed by the numerical simulations. In contrast, traditional OE retrievals exhibit bias when the prior mean used in the retrieval differs from the true mean. While the SVD approach can be used for most trace gas retrievals, it is particularly useful for situations where prior knowledge of the trace gas profile is poor. The SVD analysis is also useful in illustrating how vertical information is treated by the traditional OE approach.

[发布日期] 2018-08-27

[学科分类] 污染

[关键词] ABSORPTION SPECTROSCOPY;CARBON DIOXIDE CONCENTRATION;GAS SPECTROSCOPY;GREENHOUSE GASES;MATRICES (MATHEMATICS);SIMULATION;VERTICAL DISTRIBUTION;BAYES THEOREM;BIAS;DIFFERENTIAL ABSORPTION LIDAR;MATHEMATICAL MODELS