Honeycombed activated carbon with greatly increased specific surface by direct activation of glucose for supercapacitors

[摘要] In the production of activated carbons (ACs), glucose as a precursor is prone to producing the graphitic char intermediates after carbonization, which are difficult to be activated in the subsequent activation. In order to obtain a desirable specific surface area, either twice activation after carbonization or hydrothermal treatments of glucose before activation is applied. In this research, the direct activation of glucose has been executed to produce honeycombed ACs via deoxygenation of the glucose precursor in the KOH aqueous solution for appropriate time at room temperature. It is found that when glucose is subjected to the alkaline circumstance, dehydration and polymerization reactions increase the C/O ratio while the degradation and oxidation decrease the C/O ratio. The AC from the deoxygenated product with the highest C/O ratio has a superior specific surface area of 1912 m(2) g(-1) which is much higher than 130 m(2) g(-1) for the AC by the conventional two-step method. The Honeycombed morphology and the specific surface increased by one order of magnitude lead to good performance of 268 F g(-1) in the KOH and 24.5 Wh kg(-1) in the KBr electrolyte. (C) 2021 Elsevier B.V. All rights reserved.

[发布日期] 2021-11-25

[关键词] Direct activation;Activated carbon;Glucose;Supercapacitors