Additional complexity in the Raman spectra of U3O8

[摘要] Uranium oxides are readily amenable to investigation using Raman spectroscopy, and this technique is frequently used as a chemical analysis tool. We show, in triuranium octoxide (U3O8), the presence of previously unreported Raman peaks located below 100 cm(-1). By maximum intensity, the strongest peak in U3O8 appears at 54 cm(-1) and is resolution limited, making this mode an ideal candidate for chemically identifying U3O8 using Raman spectroscopy. Detailed peak analysis indicates that the main spectral feature between 300 and 500 cm(-1) is more accurately described by a septet than a triplet. Two samples of differing oxygen content show only minor differences in bulk crystal structure, but subtle changes in lattice dynamics are suggestive of defect scattering in analogy to UO2+x. (C) 2019 Elsevier B.V. All rights reserved.

[发布日期] 2019-12-15

[关键词] Raman spectroscopy;Uranium oxides;U3O8