Thermophysical properties and reversible phase transitions in yttrium hydride

[摘要] The thermophysical properties of yttrium hydrides were investigated as a function of temperature (room temperature [RT] to 700 degrees C) and hydrogen concentration (H/Y ratio ranges from 1.52 to 1.93). The results indicate that at the temperatures below 300 degrees C, the hydrogen content did not have a significant influence on the thermal expansion, while the specific heat capacity, the thermal diffusivity, and the calculated thermal conductivity were slightly higher for the larger H/Y ratio. Between 300 degrees C and 700 degrees C, a reversible second-order endothermic transition in all measured thermal properties was observed. It was also found that the onset temperatures of the observed transition varied, with the composition having inverse dependence on the hydrogen content. The phase transition from (alpha-Y + delta-YHx) mixed phase to the delta-YHx single phase was excluded from the main contributors to the observed transition. An attempt was made to explain the behavior of the thermophysical properties at higher temperatures by considering the order-disorder transition as a result of hydrogen redistribution. (C) 2020 Elsevier B.V. All rights reserved.

[发布日期] 2020-12-15

[关键词] Yttrium hydride;Heat capacity;Thermal diffusivity;Thermal conductivity;Thermal expansion;Phase transformation