Novel platinum group metal-free catalyst ink deposition system for combinatorial polymer electrolyte fuel cell performance evaluation

[摘要] A new system for rapid and precise fabrication of polymer electrolyte fuel cell (PEFC) membrane-electrode assemblies (MEAs) is introduced to facilitate rapid testing and characterization of platinum group metal-free (PGMfree) catalysts, with minimal waste of materials, using commercial combinatorial hardware and multi-channel potentiostat. The commercial combinatorial system, designed for high-throughput catalyst activity evaluation (i.e., low overpotential and current densities) using gas-diffusion electrodes (GDEs), has been further developed to enable simultaneous evaluation of the high current density performance on air of twenty-five cathodes prepared by coating catalyst-ionomer inks directly onto the membrane using a newly-developed deposition system. A nanopipette or micropipette coupled to a precise peristaltic pump is being used for precise and even catalyst ink deposition onto the membrane in each of twenty-five circular electrodes with areas of <1 cm(2) and in the precise locations required by the commercial combinatorial MEA hardware. The automated ink deposition system is coupled with a custom-designed heated vacuum table mounted on a computer-controlled XY stage to prevent deformation of the membrane and electrode layers during ink deposition onto the membrane. This system was utilized to evaluate the impact of ionomer to catalyst ratio on the hydrogen-air fuel cell performance of the PGM-free catalyst.

[发布日期] 2020-12-31

[关键词] PEFC electrode;Combinatorial performance evaluation;Automated fabrication system;Segmented fuel cell hardware