AMS radiocarbon dating of mortar: The case study of the medieval UNESCO site of Modena

[摘要] The carbon dioxide contributing to binder formation during the set of a lime mortar reflects the atmospheric C-14 content at the time of construction of a building. For this reason, the C-14 dating of mortars is used with increasing frequencies in archaeological and architectural research. Mortars, however, may also contain carbonaceous contaminants potentially affecting radiocarbon dating. The Centre for Isotopic Research on Cultural and Environmental heritage (CIRCE) of the Second University of Naples (SUN) has recently obtained some promising results in mortar radiocarbon dating thanks to the development of a procedure (i.e. CryoSoniC/Cryo2SoniC) aiming to eliminate exogenous C contamination that may occur in a mortar. The construction history of the UNESCO World Heritage Site of Modena (Italy) is still controversial and represents a challenging case study for the application of absolute dating methodologies for different reasons. From the point of view of C-14 dating, for example, given the high percentage of carbonate aggregates composing these samples, Modena mortars represent an experimental test particularly indicative of exogenous carbon sources suppression ensuring methodology accuracy. In this paper several AMS Radiocarbon dates were carried out on lime lumps with the aim to: (i) verify procedure accuracy by a comparison of the results obtainable from lime lumps dated after different treatments (i.e. bulk lime lumps vs. CryoSoniC purified lime lumps); (ii) compare different building phases absolute chronology for the medieval UNESCO site of Modena, with that assumed by historical sources in order to assess preliminary the C-14 dating feasibility for of the site. Historical temporal constraints and mortar clustering, based on petrography, have been applied to define a temporal framework of the analyzed structure. Moreover, a detailed petrographic characterization of mortars was used both as a preliminary tool for the choice of samples and to infer about the lack of accuracy (when verified) of the applied mortar C-14 dating procedure. (C) 2015 Elsevier B.V. All rights reserved.

[发布日期] 2015-10-15

[效力级别]  Proceedings Paper

[关键词] Mortar;Radiocarbon dating;Accelerator mass spectrometry