Indium doped Cd1-xZnxO alloys as wide window transparent conductors

[摘要] We have synthesized Indium doped Cd1-xZnxO alloys across the full composition range using magnetron sputtering method. The crystallographic structure of these alloys changes from rocksalt (RS) to wurtzite (WZ) when the Zn content is higher than 30%. The rocksalt phase alloys in the composition range 0 < x < 0.3 can be efficiently n-type doped, shifting the absorption edge to 3.25 eV and reducing resistivity to about 2.0 x 10(-4) Omega-cm. We found that In doped CdO (ICO) transmits more solar photons than commercial fluorine doped tin oxide (FTO) with comparable sheet conductivity. The infrared transmittance is further extended to longer than 1500 nm wavelengths by depositing the In doped Cd1-xZnxO in similar to 1% of O-2. This material has a potential for applications as a transparent conductor for silicon and multi-junction solar cells. (C) 2015 Elsevier B.V. All rights reserved.

[发布日期] 2015-12-31

[关键词] Transparent conducting oxides;Cadmium oxide;Zinc oxides;Full spectrum photovoltaics