Investigation of Co(OH)2 formation during cobalt electrodeposition using a chemometric procedure

[摘要] The mechanism of Co electrodeposition in sulphate solutions containing boric acid was investigated using the EQCM technique and potentiostatic measurements. The effects of solution composition, temperature and deposition potential were studied using factorial design as a chemometric procedure. The boric acid was used as a buffer to prevent pH changes due to the hydrogen evolution reaction (HER) during electrodeposition. The results showed that Co(OH)(2) was formed as a parallel reaction to metallic Co formation under some experimental conditions. The analysis of the factorial design revealed that temperature and [CO2+:H3BO3] molar ratio were the critical variables that affect the mechanism of cobalt electrodeposition. At high temperatures (48 degrees C) and using a 5:1 molar ratio of [Co2+:H3BO3], the formation of cobalt hydroxide was detected simultaneously with cobalt deposition. (C) 2010 Elsevier B.V. All rights reserved.

[发布日期] 2010-12-25

[关键词] Cobalt electrodeposition;Cobalt hydroxide;EQCM;Factorial design;Chemometric