Synthesis of benzo[c]chromen-6-ones via novel cyclic aryl-Pd(II)-ester enolate intermediates

[摘要] The examination of the palladium catalysed arylation reactions of mono-iodo derivatives of the phenyl and benzyl esters of benzoic acid, phenylacetic acid and dehydrocinnamic acid has resulted in the formation of benzo[ c] chromen-6-ones, unexpected cinnamate and succinate products and diphenyl dimers. Many of these products can be rationalised as arising from novel cyclic ArPd(II)-enolate intermediates, formed by intramolecular C-H activation by ArPd( II). Crown Copyright (c) 2007 Published by Elsevier Ltd. All rights reserved.

[发布日期] 2007-11-05