Catalytic enantioselective alkene epoxidation using novel spirocyclic N-carbethoxy-azabicyclo[3.2.1]octanones
[摘要] A general synthetic route allowing access to several spirocyclic N-carbethoxy-azabicyclo[3.2.1]octanones is developed. These novel ketones efficiently catalyse alkene epoxidation using Oxone (R) with up to 91.5% ee. (C) 2010 Elsevier Ltd. All rights reserved.
[发布日期] 2010-08-14 [发布机构]
[效力级别] Proceedings Paper [学科分类]
[关键词] Epoxidation;Asymmetric;Ketone;Dioxirane [时效性]
