Directed addition of sulfur-stabilised carbanions to 1,2,3-trisubstituted aziridines

[摘要] Thioether and sulfone-stabilised carbanions possessing varying functional groups enter into highly regioselective, stereospecific ring-opening reactions with vinyl- and hydroxymethyl-substituted aziridines. Some derivatisation reactions of the adducts are reported. (C) 2010 Elsevier Ltd. All rights reserved.

[发布日期] 2010-08-14

[效力级别]  Proceedings Paper

[关键词] Aziridine;Cyclisation;Directed addition;Regioselective;Sulfur-stabilised Carbanion