A RADICAL APPROACH TO THE SYNTHESIS OF (+/-)-SUPINIDINE
[摘要] Intramolecular addition of alpha-sulfonyl radicals to triple bonds followed by addition of tin radicals to the resulting allylsulfones gave pyrrolizidine skeletons. Subsequent manipulations led to a formal synthesis of (+/-)-supinidine.
[发布日期] 1992-12-15 [发布机构]
[效力级别] [学科分类]
[关键词] RADICAL CYCLIZATION;ALPHA-SULFONYL RADICAL;+/--SUPINIDINE;PYRROLIZIDINE ALKALOID;ALLYSTANNANE [时效性]
