Platinum-pincer introduction using active ester chemistry

[摘要] In search of a new way to attach organometallic pincer complexes to amines via an amide bond, the N-hydroxysuccinimide ester of 3,5-bis-[(dimethylamino)methyl]-4-(iodoplatino(II))-benzoic acid was synthesized. This Compound reacts with several primary amines to form the corresponding amides cleanly and in high yields. (C) 2002 Elsevier Science Ltd. All rights reserved.

[发布日期] 2002-09-09