An unexpected oxidative decarboxylation reaction of frenolicin-B

[摘要] In the presence of free radicals, frenolicin-B (I) undergoes an unexpected oxidative decarboxylation reaction to afford 2 in an overall yield of 51%. Theoretical calculations support the proposed mechanism. Copyright (C) 1996 Elsevier Science Ltd

[发布日期] 1997-01-20