Photoinduced electron transfer reactions across rigid linear spacer groups of high symmetry

[摘要] A series of highly symmetrical dienes 1-3 were prepared through [2+2] cyclo-addition of norbornadiene (NBD) in an exo-trans-exo geometry. These molecules can be utilized as spacer groups in donor(D)-spacer(S)-acceptor(A) types of electronic dyads possessing strictly linear rigidity. The electronic coupling between D and A was promoted effectively by the sigma-bonds through the all-trans spacer groups so that a highly efficient photoinduced electron transfer process takes place. The even-odd NBD dependent alternation of the D/A orientation is intriguing, which leads to an unusual correlation in the spacer tuning electron transfer process. (C) 2002 Elsevier Science Ltd. All rights reserved.

[发布日期] 2002-11-04

[关键词] rigid rod spacer;electron transfer;donor and acceptor;naphthalene;norbornadiene