A MECHANISTIC STUDY OF PYRROLE FORMATION IN THE HBF4-CATALYZED THERMOLYSIS OF CYCLOPROPYL KETIMINES

[摘要] A study of the HBF4-catalyzed rearrangement of 1-(1-piperidino)cyclopropyl ketimines to 2-substituted pyrroles has been conducted using carbon-13 labeled starting material. The results support the formation of a bicyclic aziridine-containing intermediate.

[发布日期] 1991-11-25