SINGLE ELECTRON-TRANSFER IN THE ADDITION OF CHIRAL DIPOLE-STABILIZED ORGANOLITHIUMS TO CARBONYLS - STEREOCHEMISTRY OF A CHIRAL NUCLEOPHILE AS A MECHANISTIC PROBE

[摘要] Spectroscopic and stereochemical evidence is provided which suggests that single electron transfer (SET) accounts for the difference in selectivity observed in the reaction of metalated pivalamides and oxazolines with carbonyls.

[发布日期] 1991-04-22