Supramolecular control of photochemical enantiomeric induction and radical pair recombination in zeolites

[摘要] Geminate radical pairs are formed from the alpha-photocleavage of aryl ketones within the supercage of zeolites which has been modified with chiral guest molecules. Herein, we report the supramolecular structure and dynamic control of both the enantiomeric selectivity and probability of the recombination of the radical pairs. (C) 1997 Elsevier Science Ltd.

[发布日期] 1997-04-14