CATALYTIC-OXIDATION OF HOMOALLYLALCOHOLS TO ALPHA-ALKOXYTETRAHYDROFURANS BY A PD-NITRO COMPLEX AND MOLECULAR-OXYGEN

[摘要] Various homoallylalcohols were highly regioselective oxidized with molecular oxygen at the terminal carbon to afford cyclic acetals (alpha-alkoxytetrahydrofurans) using PdNO2Cl(CH3CN)(2) as a catalyst in the presence of CuCl2 and t-butanol or isopropanol.

[发布日期] 1994-01-17