ARENETHIOLATOCOPPER(I) COMPLEXES AS HOMOGENEOUS CATALYSTS FOR MICHAEL ADDITION-REACTIONS

[摘要] Arenethiolatocopper(I) complexes are shown to be efficient homogeneous catalysts in Michael addition reactions of several Grignard reagents to acyclic enones; the addition products are formed with excellent chemoselectivity (>99%) and good enantioselectivity (76% e.e.).

[发布日期] 1994-08-15