Development of a new correction algorithm applicable to any filter-based absorption photometer

[摘要] Among the various measurement approaches to quantify the light absorption coefficient ( B abs ), filter-based absorption photometers are dominant in monitoring networks around the globe. Numerous correction algorithms have been introduced to minimize the artifacts due to the presence of the filter in these instruments. However, from our recent studies conducted during the Fire Influence on Regional and Global Environments Experiment (FIREX) laboratory campaign, corrected filter-based B abs remains biased high by roughly a factor of 2.5 when compared to a reference value using a photoacoustic instrument for biomass burning emissions. Similar overestimations of B abs from filter-based instruments exist when implementing the algorithms on 6 months of ambient data from the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) user facility from 2013 (factor of roughly 3). In both datasets, we observed an apparent dependency on single-scattering albedo (SSA) and the absorption Ångström exponent (AAE) in the agreement between B abs based on existing correction factors and the reference B abs . Consequently, we developed a new correction approach that is applicable to any filter-based absorption photometer that includes light transmission from the filter-based instrument as well as the derived AAE and SSA. For the FIREX and SGP datasets, our algorithm results in good agreement between all corrected filter-based B abs values from different filter-based instruments and the reference (slopes ≈1 and R 2 ≈0.98 for biomass burning aerosols and slopes ≈1.05 and R 2 ≈0.65 for ambient aerosols). Moreover, for both the corrected B abs and the derived optical properties (SSA and AAE), our new algorithms work better or at least as well as the two common correction algorithms applied to a particle soot absorption photometer (PSAP). The uncertainty of the new correction algorithm is estimated to be ∼10  %, considering the measurement uncertainties of the operated instruments. Therefore, our correction algorithm is applicable to any filter-based absorption photometer and has the potential to “standardize” reported results across any filter-based instrument.

[学科分类] 内科医学