Hierarchical Bimetallic Selenides CoSe 2 –MoSe 2 /rGO for Sodium/Potassium-Ion Batteries Anode: Insights into the Intercalation and Conversion Mechanism

[摘要] As anode materials for high-performance sodium-ion batteries and potassium-ion batteries, bimetallic selenides have attracted great concern due to their relatively high electrical conductivity and electrochemical activity. However, the formidable challenge in the reaction process is the large volume change, leading to the structural collapse of material, and eventually the decline in electrochemical performance. Herein, a composite of hierarchical CoSe 2 –MoSe 2 tubes anchored on reduced graphene oxide nanosheets (CoSe 2 –MoSe 2 /rGO) is designed by an in situ hydrothermal selenization treatment. Benefiting from the synergistic effects between CoSe 2 and MoSe 2 , unique hierarchical structure, and effective reduced graphene oxide coating, the CoSe 2 –MoSe 2 /rGO exhibited improved reaction kinetics and structural stability, and thus good electrochemical properties. A combination mechanism of intercalation and conversion of CoSe 2 –MoSe 2 /rGO by forming Na x CoSe 2 and Mo 15 Se 19 as intermediate states is put forward on the basis of in situ and ex situ XRD analyses.

[关键词] CoSe2;hierarchical structure;MoSe2;potassium-ion batteries;sodium-ion batteries