Origin of V-Cr-Ti-mineralization in thermally overprinted metal-rich black shales from the Teplá-Barrandian Unit (Bohemian Massif) and implications for metal remobilization during metamorphism

[摘要] We present a detailed study of geochemical composition and ore mineralogy of black shales from Chynín, Czech Republic,representing Ediacaran organic matter-rich sediments, which were subject to regional and contact metamorphism. Theyare part of the Blovice Accretionaly Complex (BAC) in the Teplá–Barrandian Unit (TBU) and are located close to thecontact with the Central Bohemian Pluton (CBP). The black shales were encountered with metasilicites, metabasalts,and basic tuffitic rocks in the CHY-2 drill hole (250 m deep) and are regionally associated with hornfels bodies. Thegeochemistry of these shales indicates that they correspond to metal-rich black shales deposited under strongly reducingconditions (TOC/Pmolar > 100, high Mo and U values). On the other hand, the lack of a positive link between TOC andredox-sensitive metals (e.g., V, U, Cr, Ni, Mo) and their generally negative correlation with sulfur indicate importantlate-stage metal and sulfur remobilization. This is reflected in the mineralogical composition of the shales, which documents a thermal event in their history. Abundant framboidal pyrite (pyrite I) was recrystallized into coarse aggregates(pyrite II), locally accompanied by chalcopyrite, sphalerite, and rare molybdenite, pentlandite and breithauptite. Abundantpyrrhotite formed there due to selective desulfurization of pyrite I and II during the contact metamorphism. Locally, thisprocess was also accompanied by the replacement of pyrrhotite by V–Cr–O (karelianite – V2O3 and eskolaite – Cr2O3,mostly with dominant karelianite end-member) and Ti–V–O (vanadium rutile, schreyerite – V2Ti3O9 and a phase withthe theoretical composition V4Ti3O12, yet unknown to the mineralogical system). Vanadium–Cr–Ti elemental associationsreported from different localities of Neoproterozoic metal-rich black shales, metal-rich black shales, and (meta)silicitesin TBU indicate similar sources of these elements but different conditions of their accumulation.

[学科分类] 自动化工程

[关键词] V–Cr–Ti oxides;metal-rich black shales;Neoproterozoic;contact metamorphism