EVALUATION OF ALTERNATIVE FILTER MEDIA FOR THE ROTARY MICROFILTER

[摘要] SRS is currently developing and testing several processes to treat high level radioactive liquid waste. These processes include the Integrated Salt Disposition Process (ISDP), the Salt Waste Processing Facility (SWPF), and the Small Column Ion Exchange Process (SCIX). Each of these processes has a solid-liquid separation process that limits its throughput. SRNL researchers identified and tested the rotary microfilter as a technology to increase solid-liquid separation throughput. The testing showed significant improvement in filter flux with the rotary microfilter over the baseline crossflow filter (i.e., 2.5-6.5X during scoping tests, as much as 10X in actual waste tests, and approximately 3X in pilot-scale tests). SRNL received funding from DOE EM-21, and subsequently DOE EM-31 to develop the rotary microfilter for high level radioactive service. The work has included upgrading the rotary microfilter for radioactive service, testing with simulated SRS waste streams, and testing it with simulated Hanford waste streams. While the filtration rate is better than that obtained during testing of crossflow filters, the authors believe the rotary microfilter throughput can be improved by using a better filter membrane. The rotary microfilter membrane is made of stainless steel (Pall PMM050). Previous testing, funded by DOE EM-21, showed that asymmetric filters composed of a ceramic membrane on top of a stainless steel support produced higher filter flux than 100% stainless steel symmetric filters in crossflow filter tests. In that testing, the Pall Accusep and Graver filters produced 13-21% larger filter flux than the baseline 0.1 {micro}m Mott filter. While the improvement in flux is not as dramatic as the improvement of the rotary filter over a crossflow filter, a 13-21% increase could reduce the lifetime of a 30 year process by 4-6 years, with significant cost savings. Subsequent rotary filter testing showed the Pall PMM050 stainless steel filter membrane produced higher flux than the Mott filter media in bench-scale and pilot-scale testing. The Accusep and Graver filter media were not evaluated in that testing, because they are not available as flat sheets. The Accusep filter was developed at ORNL and licensed to Pall Corporation. This filter has a stainless steel support structure with a zirconium oxide ceramic membrane. The pore size is 0.1 {micro}m absolute. The Graver filter has a stainless steel support structure with a titanium dioxide ceramic membrane. The pore size is 0.07 {micro}m absolute. SRNL and ORNL are working together to develop filter media similar to the Accusep and Graver media, and to test them in a bench-scale filtration apparatus to attempt to improve the throughput of the rotary microfilter. This report describes the effort.

[发布日期] 2011-09-13

[学科分类] 材料科学（综合）

[关键词] CERAMICS;EVALUATION;FILTRATION;ION EXCHANGE;LIFETIME;LIQUID WASTES;MEMBRANES;ORNL;STAINLESS STEELS;TESTING;TITANIUM;WASTE PROCESSING;WASTES;ZIRCONIUM OXIDES