Thermodynamic Studies to Support Actinide/Lanthanide Separations

[摘要] Thermodynamic data on the complexation of Np(V) with HEDTA in a wide pH region were re-modeled by including a dimeric complex species, (NpO₂)₂(OH)₂L₂^6- where L^3- stands for the fully deprotonated HEDTA ligand and better fits were achieved for the spectrophotometric data. The presence of the dimeric complex species in high pH region was verified for the first time by the EXAFS experiments at Stanford Synchrotron Radiation Laboratory (SSRL).

[发布日期] 2016-09-04

[学科分类] 化学（综合）