Rate Theory Modeling and Simulation of Silicide Fuel at LWR Conditions

[摘要] As a promising candidate for the accident tolerant fuel (ATF) used in light water reactors (LWRs), the fuel performance of uranium silicide (U₃Si₂) at LWR conditions need to be well-understood. In this report, rate theory model was developed based on existing experimental data and density functional theory (DFT) calculations so as to predict the fission gas behavior in U₃Si₂ at LWR conditions. The fission gas behavior of U₃Si₂ can be divided into three temperature regimes. During steady-state operation, the majority of the fission gas stays in intragranular bubbles, whereas the dominance of intergranular bubbles and fission gas release only occurs beyond 1000 K. The steady-state rate theory model was also used as reference to establish a gaseous swelling correlation of U₃Si₂ for the BISON code. Meanwhile, the overpressurized bubble model was also developed so that the fission gas behavior at LOCA can be simulated. LOCA simulation showed that intragranular bubbles are still dominant after a 70 second LOCA, resulting in a controllable gaseous swelling. The fission gas behavior of U₃Si₂ at LWR conditions is benign according to the rate theory prediction at both steady-state and LOCA conditions, which provides important references to the qualification of U₃Si₂ as a LWR fuel material with excellent fuel performance and enhanced accident tolerance.

[发布日期] 2016-08-29

[学科分类] 核能源与工程