Investigation of Interrelation between Deformation, Composition and Structural Characteristics of Magnesium Oxychloride Cements

[摘要] The paper studies the process of volume deformation changes in magnesium cement at its hardening in accordance with its composition and structural peculiarities, which result from the roasting parameters of the raw materials. The study has been carried out with the aim of broadening raw materials sources for production of magnesia cements and construction materials through the use waste products of ore-dressing and processing enterprises. The mineralogical and phase composition of magnesium cements, obtained on the basis of magnesite with high content of impurity minerals from the mine dumps, has been studied by the X-ray phase analysis and derivatography. The roasting of the initial raw materials was carried out at various temperature conditions in order to get cements of different activities. The typical content of hydrated phases has been found for the hardened magnesian stone obtained from cements with different activity degrees. The characteristics of volume deformations developed in the magnesian stone have been described in relation to its phase composition. The influence of low- and high-activity crystals and calcium oxide crystals on the soundness and the structural integrity of magnesian stone has been covered.

[发布机构] Department of Building Materials and Products, South Ural State University, Lenin Avenue, 76, Chelyabinsk; 454080, Russia^1

[学科分类] 土木及结构工程学

[关键词] Impurity minerals;Magnesia cements;Magnesium oxychloride cement;Structural characteristics;Structural peculiarities;Temperature conditions;Volume deformation;X-ray phase analysis