Obtaining and characterization of La0.8Sr0.2CrO3 perovskite by the combustion method

[摘要] This research is focused on the synthesis and characterization of a perovskite oxide based on La0.8Sr0.2CrO3system by the combustion method. The material was obtained in order to contribute to analyse the effect of synthesis route in the obtaining of advanced anodic materials for solid oxide fuel cells (SOFC). The obtaining of solid was achieved starting from corresponding nitrate dissolutions, which were polymerized by temperature effect in presence of citric acid. The solid precursor as a foam citrate was characterized by infrared (FTIR) and ultraviolet (UV) spectroscopy, confirming the effectiveness in synthesis process. The solid was calcined in oxygen atmosphere at 800°C and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive of X-ray spectroscopy (EDX) and solid state impedance spectroscopy (IS). Results confirm the obtaining of an orthorhombic solid with space group Pnma (62) and cell parameters a=5.4590Å, b=7.7310Å and c=5.5050Å. At morphological level the solid showed a heterogeneous distribution with an optimal correspondence with proposed and obtained stoichiometry. The electrical characterization, confirm a semiconductor behaviour with a value of 2.14eV Band-gap according with previous works.

[发布机构] Universidad Pedagógica y Tecnológica de Colombia, Boyacá, Tunja, Colombia^1

[效力级别] 化学

[关键词] Electrical characterization;Energy dispersive;Heterogeneous distributions;Impedance spectroscopy;Oxygen atmosphere;Perovskite oxides;Semiconductor behaviours;Synthesis and characterizations