Relativistic photoionization delays and the role of auto-ionizing resonances

[摘要] We measured the relative ionization delays into the two spin-orbit components of the electronic ground states of Xe+and Kr+under the inuence of auto-ionizing intermediate and final states. The results are in good agreement with state-of-the-art calculations based on the time-dependent configuration-interaction singles (TDCIS) approach.

[发布机构] Laboratory for Physical Chemistry, ETH Zurich, Vladimir-Prelog-Weg 2, Zurich; CH-8093, Switzerland^1;Center for Free-Electron Laser Science, DESY, Notkestrasse 85, Hamburg; 22607, Germany^2;ITAMP, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge; MA; 02138, United States^3

[关键词] Configuration interaction singles;Electronic ground state;Final state;Spin orbits;State of the art;Time dependent