Miniature Fuel Cell With Monolithically Fabricated Si Electrodes - Au-Pd-Pt Multilayer Catalyst -

[摘要] A novel catalyst layer structure is proposed for our miniature fuel cells. In our fuel cells, conventionally porous Pt was used as a catalyst layer. In order to reduce the Pt amount, instead of porous Pt, porous Pd was formed on a Si chip and Pt was deposited atomically on the Pd by UPD-SLRR(Under Potential Deposition - Surface Limited Redox Replacement). The Pd- Pt catalyst showed satisfying performance, besides high CO tolerance was observed. Though the Pd-Pt catalyst is quite promising, Pd is also a rare metal and reduction of Pd amount is necessary. In this study, a novel Au-Pd-Pt catalyst formation strategy is proposed by UPD-SLRR, and the layered structure is preliminary fabricated.

[发布机构] Tokyo Unversity of Science, 2641 Yamazaki, Chiba, Noda; 278-8510, Japan^1;University of Bristol, Tyndall Avenue, Bristol; BS8 1TL, United Kingdom^2

[效力级别] 能源学

[关键词] Catalyst layers;CO tolerance;Layered Structures;Miniature fuel cells;Novel catalysts;Pd Pt catalyst;Si electrodes;Underpotential deposition