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Mössbauer Effect Studies in Yttrium Based Metallic Glasses
[摘要]

The short range order of a variety of Yttrium-3d transition metal glasses has been investigated using Fe57 Mössbauer Effect (ME) spectroscopy. We found that the ME spectra of these glasses could best be described in terms of a model which assumes two kinds of sites for the 3d elements. The nature of the two sites is radically different depending on whether the transition metal is Mn, Fe, Co, and Ni or Cu and Zn. We attributed the difference in the structure of these glasses to the same factors which determine whether a C-15 crystalline compound is stable in equilibrium. The microscopic nature of ME spectroscopy provides an interesting comparison between the nature of the short range order in crystalline and amorphous alloys. The process of crystallization has also been studied for a few glasses, and was found to occur in two distinct steps associated with the formation of hcp Y and a C-15 compound. In the final section we use the results of this study to design a novel high field superconducting material.

[发布日期]  [发布机构] University:California Institute of Technology;Department:Engineering and Applied Science
[效力级别]  [学科分类] 
[关键词] Applied Physics [时效性] 
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