Numerical Modelling of a Fast Pyrolysis Process in a Bubbling Fluidized Bed Reactor

[摘要] In this study, the Eulerian-Granular approach is applied to simulate a fast pyrolysis bubbling fluidized bed reactor. Fast pyrolysis converts biomass to bio-products through thermochemical conversion in absence of oxygen. The aim of this study is to employ a numerical framework for simulation of the fast pyrolysis process and extend this to more complex reactor geometries. The framework first needs to be validated and this was accomplished by modelling a lab-scale pyrolysis fluidized bed reactor in 2-D and comparing with published data. A multi-phase CFD model has been employed to obtain clearer insights into the physical phenomena associated with flow dynamics and heat transfer, and by extension the impact on reaction rates. Biomass thermally decomposes to solid, condensable and non-condensable and therefore a multi-fluid model is used. A simplified reaction model is sued where the many components are grouped into a solid reacting phase, condensable/non-condensable phase, and non-reacting solid phase (the heat carrier). The biomass decomposition is simplified to four reaction mechanisms based on the thermal decomposition of cellulose. A time-splitting method is used for coupling of multi-fluid model and reaction rates. A good agreement is witnessed in the products yield between the CFD simulation and the experiment.

[发布机构] Australian Maritime College, National Centre of Maritime Engineering and Hydrodynamics, University of Tasmania, Launceston; TAS, Australia^1;Faculty of Engineering and Applied Science, Memorial University, St. John's; NL, Canada^2

[效力级别] 经济学

[关键词] Bubbling fluidized bed reactor;Fast pyrolysis process;Fluidized bed reactors;Multi-fluid models;Physical phenomena;Reaction mechanism;Thermochemical Conversion;Time-splitting methods