Characterization of Malaysian coals for carbon dioxide sequestration

[摘要] Coal samples from Mukah-Balingian and Merit-Pila coal mines were characterized with ultimate, approximate, petrographic analysis, FT-IR spectra patterns, FESEM images and BET measurements to obtain information on the chemical composition and chemical structure in the samples. Two coal samples were obtained from Merit-Pila coal mine namely sample1 (S1) and sample2 (S2). The other two coal samples were obtained from Mukah-Balingian coal mine namely sample3 (S3) and sample4 (S4), Sarawak, Malaysia. The results of ultimate analysis show that coal S1 has the highest carbon percentage by 54.47%, the highest hydrogen percentage by 10.56% and the lowest sulfur percentage by 0.19% and the coal S4 has the highest moisture content by 31.5%. The coal S1 has the highest fixed carbon percentage by 42.6%. The coal S4 has BET surface area by 2.39 m2/g and Langmuir surface area by 3.0684 m2/g respectively. Fourier-Transform Infrared (FT-IR) spectroscopy analysis of all coal samples shows a presence of oxygen containing functional groups which considered are as active sites on coal surface. The oxygen functional groups are mainly carboxyl (-COOH), hydroxyl (-OH), alkyl (-CH, -CH2, -CH3), aliphatic (C-O-C stretching associated with -OH), amino (-NH stretching vibrations), (-NH stretching vibrations), aromatic (C=C), vinylic (C=C) and clay minerals. In all FE-SEM images of coal samples matrix, it can be seen that there are luminous and as non luminous features which refer to the existence of various minerals types distributed in the coal organic matrix. The bright luminosity is due to the presence of sodium, potassium or aluminium. According to petrographic analysis, all coal sample samples are range in vitrinite reflectance from 0.38% to 56% (VRr) are sub-bituminous coals.

[发布机构] Chemical Engineering Department, Universiti Teknologi PETRONAS, Tronoh, Perak; 31750, Malaysia^1;Chemical Engineering Department, Benha Faculty of Engineering, Benha University, Benha, Egypt^2

[效力级别] 化学 [学科分类] 生物科学（综合）

[关键词] Carbon dioxide sequestration;Chemical compositions;Fourier transform infra red (FTIR) spectroscopy;Oxygen functional groups;Oxygen-containing functional groups;Petrographic analysis;Stretching vibrations;Vitrinite reflectance