Irradiation Effect on Stability of Plasticized Poly(Fluorostyrene) Isomers in Solution

[摘要] The UV irradiation and blending effects on stability of Poly(Fluorostyrene) isomers in solution were studied at different intervals of irradiation time in presence of air. The increase in irradiation time of these isomers caused an increase in the intensity of the absorption band and an increase in the intensity of the absorption of new broad band at longer wavelength, thus indicating a possibility of photodegradation of polymeric chains. The influence of added dioctyl phthalate and dioctyl terephthalate plasticizers on photooxidative degradation was also investigated and was found to increase the photodegradation processes in polymeric chains. On the other hand, the intensity of excimer and monomer fluorescence bands maxima was also found to decrease with increase in irradiation times. These changes may be attributed to the formation of new photoproducts resulted from the photodegradation of irradiated polymeric chains. The decrease in polarity of used solvents caused a considerable enhancement to the intensity of the polymer fluorescence band and accelerated photodegradation. A proposed mechanism is suggested to account for the effects of added plasticizers, the increase in irradiation time, and polarity of solvents on photodegradation and photooxidation processes in polymeric chains.

[学科分类] 物理化学和理论化学