Photoinduced Change of UV-Absorption and Redox Potential of Alkyne-Bridged Diferrocenyl Azobenzene Derivative

[摘要] An alkynyl-coupled diferrocenylpropane and azobenzene derivative has been synthesized. Photoinduced change of UV-absorbance and shifts of redox potential of synthesized compound were elucidated by time-dependent density function theory (TD-DFT) calculations, indicating that isomerization of trans to cis configuration occurs by UV irradiation.

[学科分类] 无机化学