Role of Polymer Interactions with Clays and Modifiers on Nanomechanical Properties and Crystallinity in Polymer Clay Nanocomposites

[摘要] We present the effect of organic modifier on crystallinity and nanomechanical properties of polymer clay nanocomposites (PCNs) using two different polymers while maintaining the same nanoclay and organic modifier. Experimental results and interaction energy maps of Polybutylene-Terephthalate- (PBT-) PCN system indicate that the underlying mechanisms of change in crystallinity and improvement in mechanical properties as proposed in altered phase theory are valid. Experimental and molecular simulation studies of PBT-PCN and Nylon6-PCN reveal that a higher crystallinity polymer could require significantly higher attractive and repulsive interaction energies between polymer and organic modifiers to change the crystallinity of the polymer in the PCN significantly and thus improve mechanical properties of the PCN.

[学科分类] 材料工程