The Progress ofTiO2Nanocrystals Doped with Rare Earth Ions

[摘要] In the past decades, TiO2nanocrystals (NCs) have been widely studied in the fields of photoelectric devices, optical communication, and environment for their stability in aqueous solution, being nontoxic, cheapness, and so on. Among the three crystalline phases of TiO2, anatase TiO2NCs are the best crystallized phase of solar energy conversion. However, the disadvantages of high band gap energy (3.2 ev) and the long lifetime of photogenerated electrons and holes limit its photocatalytic activity severely. Therefore, TiO2NCs doped with metal ions is available way to inhibit the transformation from anatase to rutile. Besides, these metal ions will concentrate on the surface of TiO2NCs. All above can enhance the photoactivity of TiO2NCs. In this paper, we mainly outlined the different characterization brought about in the aspect of nanooptics and photocatalytics due to metal ions added in. Also, the paper mainly concentrated on the progress of TiO2NCs doped with rare earth (RE) ions.

[学科分类] 材料工程