Experimental Study of Closed System in the Chlorine Dioxide-Iodide-Sulfuric Acid Reaction by UV-Vis Spectrophotometric Method

[摘要] The mole ratior(r=[I−]0/[ClO2]0)has great influence on ClO2-I−-H2SO4closed reaction system. By changing the initiate concentration of potassium iodide, the curve of absorbance along with the reaction time was obtained at 350 nm and 297 nm for triiodide ion, and 460 nm for iodine. The changing point of the absorbance curve's shape locates atr=6.00. For the reaction of ClO2-I−in the absence of H2SO4, the curve of absorbance along with the reaction time can be obtained at 350 nm for triiodide ion, 460 nm for iodine. The mole ratioris equal to 1.00 is the changing point of the curve's shape no matter at which wavelength to determine the reaction. For the reaction of ClO2-I−-H+in different pH buffer solution, the curve of absorbance along with the reaction time was recorded at 460 nm for iodine. Whenris greater than 1.00, the transition point of the curve's shape locates at pH 2.0, which is also the point of producing chlorite or chloride for chlorine dioxide at different pH. Whenris less than 1.00, the transition point locates at pH 7.0.

[学科分类] 分析化学