A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

[摘要] The synthesis of newtrans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ringare described. All of the synthesized products were characterized by1H-N.M.R.,13C-N.M.R., and H.R.M.S.Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined.

[学科分类] 物理化学和理论化学