SmBa2NbO6Nanopowders, an Effective Percolation Network Medium for YBCO Superconductors

[摘要] The percolation behavior of superconductor-insulator composite, YBa2Cu3O7–δ, and nano SmBa2NbO2synthesized by modified combustion technique was studied. Particle size of nano SmBa2NBO6was determined using transmission electron microscopy. The chemical nonreactivity of nano SmBa2NbO6with YBCO is evident from the X-Ray diffraction study which makes it a suitable nanoceramic substrate material for high temperature superconducting films. A systematic increase in the sintered density, approaching the optimum value of the insulating nanophase is clearly observed, as the vol.% of YBCO in the composite decreases. SEM micrograph showed uniform distribution of nanopowder among the large clusters of YBCO. The obtained percolation threshold is~26 vol% of YBCO in the composite. All the composites below the threshold value showedTC(0)~92 K even though the room resistivity increases with increase in vol.% of nano SmBa2NbO6. The values of critical exponents obtained matches well with the theoretically expected ones for an ideal superconductor-insulator system.

[学科分类] 材料工程