Microwave-Promoted Synthesis of Sulfonated Metallophthalocyanines and Aggregation in Different Solvents

[摘要] Five metallosulfophthalocyanines (Fe, Ni, Zn, Co, and Cu) compounds were synthesizedby microwave irradiation. Compared to the conventional method of synthesis in terms of reaction time and yields, the microwave-promoted synthesis is preferred with high product yield and short reaction time. All synthesized products were characterized with MALDI-TOF mass spectrum, Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), and X-ray diffraction (XRD). Aggregation behavior of the five metallosulfophthalocyanines (MSPc) in different solvents was studied by UV-Vis spectroscopy separately in N,N-dimethyl formamide (DMF) and NaOH aqueous solution (5%wt). A redshift of maximum absorption wavelength and deviations from Lambert-Beer law with increasing the concentration were observed. The dimerization equilibrium constants (K) of the five MSPc were determined, respectively.

[学科分类] 材料工程