Design and operation of an autosamplercontrolled flow-injection preconcentrationsystem for lead determination by flameatomic absorption spectrometry

[摘要] Flow-injection manifolds are described which allow the preconcentrationof lead for flame atomic absorption determinations, usingcolumns contained within the sample loop of an injection valve. Aninterface was designed which allowed the valves and pump in thesystem to be controlled by an autosampler which enabled precisetiming of preconcentration and elution steps. The effects of sampleflow rate, buffer pH and buffer type for preconcentration andeluent concentration and flow rate were investigated in order toobtain optimum performance of the system. A 50-times improvementin detection limits over conventional sample introduction wasobtained for a sample volume of approximately 12 ml, preconcentrated for150 s. The injection of eluent, as opposed to the use of acontinuously flowing eluent stream, enabled this reagent to beconserved.

[学科分类] 分析化学