Asymmetric Diels-Alder Reactions of Acylnitroso Compounds

[摘要] The Diels-Alder cycloaddition reactions of a small selection of transient C-nitroso compounds (two achiral and one chiral) were carried out with the unsymmetrically substituted, conjugated diene (E)-penta-1,3-diene 111 (piperylene). The aim of these experiments was to study the regiochemistry and any associated asymmetric induction of the cycloadducts. Acetohydroxamic acid 182d was oxidized, with periodate, in the presence of (E)-penta-1,3-diene 111 at 0

[发布机构] University:University of Glasgow

[关键词] Organic chemistry