THE RATE OF EMULSION POLYMERIZATION OF ACRYLONITRILE

[摘要] References(10)Cited-By(3)The rate of emulsion polymerization of acrylonitrile has been investigated under widely variable experimental conditions such as initiator concentration, emulsifier concentration and monomer-water ratio. The results obtained were interpreted reasonably well by kinetic equations, which were proposed by assuming that the reaction in polymer particles proceeds under the slow termination regime and that the surface of polymer particles alone plays a role in propagation.