Synthesis of the iron(II)-nitrogen complex: concepts of reactivity and back-bonding for undergraduate chemistry students
[摘要] There has been a considerable interest in coordination complexes of molecular nitrogen (N2), partly due to a possible relationship between such complexes and the nitrogen activation process in nature. The present paper describes the synthesis and infrared spectroscopic characterization of an iron-nitrogen derivative with ethylenediamine-N,N,N',N'-tetraacetate (edta) as an experiment for an undergraduate course. The topics covered here include synthesis, reactivity and spectroscopy.
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[效力级别] [学科分类] 化学(综合)
[关键词] iron;edta;dinitrogen. [时效性]