Crystal growth and comparison of vibrational and thermal properties of semi-organic nonlinear optical materials

[摘要] Single crystals of urea thiourea mercuric sulphate (UTHS) and urea thiourea mercuric chloride (UTHC), semi-organic nonlinear optical materials, were grown by low-temperature solution growth technique by slow evaporation method using water as the solvent. Good quality single crystals were grown within three weeks. The nonlinear nature of the crystals was confirmed by SHG test. The UV–Vis spectrum showed the transmitting ability of the crystals in the entire visible region. FTIR spectrum was recorded and vibrational assignments were made. The degree of dopant inclusion was ascertained by AAS. The TGA–DTA studies showed the thermal properties of the crystals.

[学科分类] 物理（综合）

[关键词] Urea thiourea mercuric sulphate;urea thiourea mercuric chloride;nonlinear optic crystals;ultraviolet–visible;Fourier transform infrared;atomic absorption spectroscopy;thermogravimetric analysis;differential thermogram analysis;second harmonic generation.