[摘要] A spectroscopic study of the flavocytochrome b enzyme, cellobiose oxidase, employing optical, NMR, EPR and near infra-red MCD techniques, has identified the axial ligands of the b-type haem. These are a histidine and a methionine, and this ligation set is discussed in relation to the functional role of the haem group.
[发布日期] [发布机构]
[效力级别] [学科分类] 生物化学/生物物理
[关键词] Cellobiose oxidase;Flavocytochrome b;Electron paramagnetic resonance;Nuclear magnetic resonance;Magnetic circular dichroism;D2O/HOD;deuterium oxide/deuterium hydroxide ϵ;extinction coefficient;EPR;electron paramagnetic resonance;FAD;flavin adenine dinucleotide;His;histidine;MCD;magnetic circular dichroism;Met;methionine;NMR;nuclear magnetic resonance [时效性]
