Partial Molal Volumes of Anilinium Chloride in Isopropanol-Water Mixtures

[摘要] Determination of partial molal volumes of anilinium chloride isopropanol-water mixtures at 30.00¡Æshowed a distinct minimum at 0.20 mole fraction isopropanol. This was interpreted as maximum in electrostriction effect and minimum in water structure. The depth in V¡Æfor alcohol-water mixtures was in the order MeOH > i-PrOH > EtOH, which indicated the importance of microscopic structure around ions.

[学科分类] 化学（综合）