Determination of Reactivities by MO (). Theoretical Studies on Phenolic Antioxidants

[摘要] Radical formation reaction of phenolic antioxidants were examined MO theoretically. Results show that substitution of electron-donating alkyl groups in phenol increases the rate of phenoxy radical formation when attacked by an electrophilic radical by stabilization of cationic transition state.

[学科分类] 化学（综合）