Halogen Exchange Reactions of Benzyl Halides (Part 1) Kinetics of Reactions of Chloride and Bromide Ions with Benzyl Chloride and Bromide

[摘要] Kinetics of reactions of chloride and bromide ions with benzyl chloride and bromide have been investigated in 90% ethanol solution. Semi-quantitative analysis of the results shows that the bond-formation is more important than the bond-breaking and furthermore in bond-formation the energy gain due to bond-formation is less than the increase in electron affinity of the nucleophile.

[学科分类] 化学（综合）